1351511-31-3Relevant articles and documents
Regio- and enantioselective hydroamination of dienes by gold(I)/menthol cooperative catalysis
Kanno, Osamu,Kuriyama, Wataru,Wang, Z. Jane,Toste, F. Dean
, p. 9919 - 9922 (2011/12/02)
Alcohol is key: Regio- and enantioselective hydroamination of 1,3-dienes has been achieved with the dinuclear catalyst (R)-DTBM-SEGPHOS. The rate and selectivity of the reaction are enhanced by alcohol additives like menthol, which coordinates the cationic gold(I) to generate a Br?nsted acid that can participate in catalysis. Mbs=p-methoxybenzenesulfonyl. Copyright