1351521-21-5

Basic information

• Product Name: [((2,6-iPrC₆H₃)NCMe)2CH]ZnPHPh
• CAS NO: 1351521-21-5
• Molecular Weight: 592.135
• Mol File: 1351521-21-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [((2,6-iPrC₆H₃)NCMe)2CH]ZnPHPh(CAS DataBase Reference)
• NIST Chemistry Reference: [((2,6-iPrC₆H₃)NCMe)2CH]ZnPHPh(1351521-21-5)
• EPA Substance Registry System: [((2,6-iPrC₆H₃)NCMe)2CH]ZnPHPh(1351521-21-5)

Safety Data

• Hazardous Substances Data: 1351521-21-5(Hazardous Substances Data)

Upstream product

• 215808-47-2 (2-((2,6-diisopropylphenyl)amido)-4-((2,6-diisopropylphenyl)imino)-2-pentene)ethylzinc 
• 638-21-1 phenylphosphane 

Relevant articles and documents

Synthesis and characterization of zinc complexes and reactivity with primary phosphines

Zinc complexes of chelating monoanionic N-donors and neutral diphosphine ligands were synthesized by reaction of diethylzinc with 1,3-diketimine, diazabutadiene, and diphosphine ligand precursors. These complexes were reacted with primary phosphines in an attempt to solicit phosphine dehydrocoupling reactivity. In most cases, insoluble zinc-containing precipitates were formed and ligands were liberated. For the most sterically encumbered complex, ( DippL)ZnEt (3, DippL = [(2,6-iPrC 6H3)NC(CH3)]2CH-), a product assigned as the zinc-phosphide (DippL)ZnPHPh (6) was observed but could not be isolated as a pure compound. A new, less bulky β-diketiminate complex (TolL)ZnEt (2, TolL = [(p-CH3C6H4)NC(CH3)] 2CH-) was reacted with primary phosphines to give a precipitate and the bis(β-diketiminate)zinc complex (TolL) 2Zn (5), an apparent product of comproportionation. ( MesAI)ZnEt (1, MesAI = MesNC(Me)(Et)C(Me) = NMes) and 2 were structurally characterized.