135186-55-9Relevant academic research and scientific papers
Synthetic Approaches to Phorbols via the Intramolecular Diels-Alder Reactions of Furans (IMDAF): Oxygen Bridge Cleavage and High Stereocontrol during Cycloaddition using α'-Benzylthio Substituted Furan Substrates
Harwood, Laurence M.,Ishikawa, Tsutomu,Phillips, Helen,Watkin, David
, p. 527 - 530 (2007/10/02)
High pressure mediated IMDAF of the α'-benzylthiofuran substrate 1 results in efficient and highly stereoselective cycloaddition; subsequent epimerisation of the cycloadduct 6 is regiospecific and the oxygen bridge may be opened by elimination or hydrolys
