1351983-10-2Relevant academic research and scientific papers
On the stereoselective bicyclization of aminodienes catalyzed by chelating diamide complexes of the group 3 metals. A direct comparison of Sc(iii) and Y(iii) bis(amide)s with an application to the synthesis of alkaloid 195F
Jiang, Tao,Livinghouse, Tom,Lovick, Helena M.
, p. 12861 - 12863 (2012/02/02)
Highly diastereoselective bicyclizations of aminodienes catalyzed by chelating diamide complexes of Sc(iii) and Y(iii) that lead to pyrrolizidines and indolizidines are described. This bis(annulation) procedure has been utilized in a concise synthesis of the pyrrolizidine alkaloid 195F.
