1352007-25-0Relevant articles and documents
SN2′ Alkylation of cyclopropanols via homoenolates
Das, Pragna Pratic,Belmore, Ken,Cha, Jin Kun
, p. 9517 - 9520 (2012)
Reining in reactivity: Stereoselective SN2′ alkylation of cyclopropanols has been devised under the control of mixed zinc/copper reagents. This method provides convenient access to enantiopure keto homoenolates which react with electrophiles (E
Palladium-catalyzed decarboxylation of allenyl 3-oxoalkanoates: An efficient synthesis of 3,4-allenyl ketones
Wan, Baoqiang,Jia, Guochen,Ma, Shengming
supporting information; experimental part, p. 46 - 49 (2012/02/15)
An efficient synthesis of 3,4-allenyl ketones via the Pd-catalyzed decarboxylative coupling of the readily available 3-oxoalkanoates is reported. The C-C bond forming reaction occurs under mild conditions producing CO 2 as the only byproduct.