1352010-08-2Relevant academic research and scientific papers
Copper-catalyzed oxidative alkynylation of diaryl imines with terminal alkynes: A facile synthesis of ynimines
Laouiti, Anouar,Rammah, Mohamed M.,Rammah, Mohamed B.,Marrot, Jerome,Couty, Francois,Evano, Gwilherm
supporting information; experimental part, p. 6 - 9 (2012/02/14)
An efficient copper-mediated method for the oxidative alkynylation of diaryl imines with terminal alkynes is reported. This reaction provides the first catalytic and general synthesis of ynimines and allows for an easy preparation of these useful building blocks. An improved copper-catalyzed oxidative dimerization of imines to azines and the synthesis of dienes and azadienes from ynimines are also described.
