135214-15-2Relevant academic research and scientific papers
THE REACTION OF THIOLS WITH : RHODIUM THIOLATE COMPLEXES AND HYDROGENATION CATALYSTS
Carlton, Laurence
, p. 231 - 234 (2007/10/02)
The unstable complexes (R = Pri, CH3(CH2)11, C6F5) formed by the reaction of RSH with are catalysts for the homogeneous hydrogenation of cyclohexene at ambient temperature and pressure.Their catalytic activity is
The reaction of with thiols: a 1H and 31P NMR study
Carlton, Laurence,Bulbulia, Zaid
, p. 139 - 147 (2007/10/02)
In toluene or THF at -40 deg C (RhH(PPh3)4> reacts with RSH (R = Pri, Ph, CH2Ph) to give the unstable dihydro complex .At 20 deg C decomposition of this complex with loss of H2 occurs via a five-coordinate species RhH2(SR)(PPh
