13522-79-7Relevant academic research and scientific papers
Synthesis of meta-Arylated Phenol Derivatives by Rhodium(I)-Catalyzed Arylation of Quinone Monoacetal
Huang, Jianhang,Liu, Na,Lu, Tao,Dou, Xiaowei
, p. 3466 - 3470 (2018)
The first selective synthesis of meta-arylphenol derivatives by arylation of quinone monoacetal is reported. The transformation was achieved under Rh(I) catalysis via a formal arylation/demethoxylation process, and valuable meta-arylphenols were obtained in high yields under mild conditions. Remarkably, an unprecedented convergent reaction pathway was assumed to be involved. (Figure presented.).
