13522-82-2 Usage
Description
[1,1'-Biphenyl]-2-ol, 5-methoxyis a chemical compound characterized by its molecular formula C14H12O2. It is a derivative of biphenyl, which features two linked phenyl rings. [1,1'-Biphenyl]-2-ol, 5-methoxyis distinguished by the presence of a methoxy group (CH3O) at the 5th position on the biphenyl ring. [1,1'-Biphenyl]-2-ol, 5-methoxyis known for its applications in organic synthesis and as a key component in the development of pharmaceutical drugs and agrochemicals. Additionally, it has been investigated for its potential biological activities, such as anti-inflammatory and antioxidant properties.
Uses
Used in Pharmaceutical Industry:
[1,1'-Biphenyl]-2-ol, 5-methoxyis used as a building block for the development of pharmaceutical drugs due to its unique chemical structure and potential biological activities. Its anti-inflammatory and antioxidant properties make it a promising candidate for the treatment of various conditions and diseases.
Used in Agrochemical Industry:
In the agrochemical industry, [1,1'-Biphenyl]-2-ol, 5-methoxyis utilized as a component in the synthesis of various agrochemicals. Its chemical properties contribute to the development of effective products for agricultural applications, such as pesticides and herbicides.
Used in Organic Synthesis:
[1,1'-Biphenyl]-2-ol, 5-methoxyis also employed in organic synthesis, where it serves as an essential intermediate for the creation of more complex molecules. Its unique structure allows for further chemical modifications, enabling the synthesis of a wide range of compounds with diverse applications in various industries.
Check Digit Verification of cas no
The CAS Registry Mumber 13522-82-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,5,2 and 2 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 13522-82:
(7*1)+(6*3)+(5*5)+(4*2)+(3*2)+(2*8)+(1*2)=82
82 % 10 = 2
So 13522-82-2 is a valid CAS Registry Number.
13522-82-2Relevant articles and documents
Mechanisms of the photochemical rearrangement of diphenyl ethers
Haga, Naoki,Takayanagi, Hiroaki
, p. 735 - 745 (1996)
The mechanism of the photochemical rearrangement of diphenyl ether (1a) was studied. Irradiation of 1a in ethanol gave 2-phenylphenol (2, 42%) and 4-phenylphenol (3, 11%) as rearrangement products, in addition to phenol (4, 30%) and benzene (5, 25%) as diffusion products. Cross-coupling experiments employing [2H10]1a demonstrated that the formation of 2- and 4-phenylphenol was an intramolecular process. Irradiation of 1a in benzene or in toluene gave biphenyls in good yields. The combined yields of rearrangement products (2 and 3) increased with increase of solvent viscosity, with a concomitant decrease in the formation of 4. All the results can be rationalized in terms of excitation of 1a to the singlet state and dissociation to a radical pair intermediate involving phenoxy and phenyl radicals. Intramolecular recombination of these radicals gives rearrangement products, and escape followed by hydrogen abstraction from the solvent gives diffusion products. When position 4 of 1a was occupied by an electron-donating substituent (1b-e), aryloxy-phenyl bond cleavage to give the corresponding rearrangement products prevailed over phenoxy-aryl bond cleavage. The opposite was the case for substrates with an electron-withdrawing substituent at position 4 (1h,i).
