1352406-02-0

Basic information

• Product Name: ((3R,3aS,4S,6aS)-4-((2R,3R)-4-(benzyloxy)-3-(ethanoyloxy)-2-methylbutyl)-3a-hydroxy-1,3-dimethyl-2,6-dioxohexahydro-1H-furo[3,4-b]pyrrol-6a-yl)methyl ethanoate
• Synonyms: ((3R,3aS,4S,6aS)-4-((2R,3R)-4-(benzyloxy)-3-(ethanoyloxy)-2-methylbutyl)-3a-hydroxy-1,3-dimethyl-2,6-dioxohexahydro-1H-furo[3,4-b]pyrrol-6a-yl)methyl ethanoate
• CAS NO: 1352406-02-0
• Molecular Weight: 491.538
• Mol File: 1352406-02-0.mol

Chemical Properties

• CAS DataBase Reference: ((3R,3aS,4S,6aS)-4-((2R,3R)-4-(benzyloxy)-3-(ethanoyloxy)-2-methylbutyl)-3a-hydroxy-1,3-dimethyl-2,6-dioxohexahydro-1H-furo[3,4-b]pyrrol-6a-yl)methyl ethanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ((3R,3aS,4S,6aS)-4-((2R,3R)-4-(benzyloxy)-3-(ethanoyloxy)-2-methylbutyl)-3a-hydroxy-1,3-dimethyl-2,6-dioxohexahydro-1H-furo[3,4-b]pyrrol-6a-yl)methyl ethanoate(1352406-02-0)
• EPA Substance Registry System: ((3R,3aS,4S,6aS)-4-((2R,3R)-4-(benzyloxy)-3-(ethanoyloxy)-2-methylbutyl)-3a-hydroxy-1,3-dimethyl-2,6-dioxohexahydro-1H-furo[3,4-b]pyrrol-6a-yl)methyl ethanoate(1352406-02-0)

Safety Data

• Hazardous Substances Data: 1352406-02-0(Hazardous Substances Data)

Upstream product

• 1352405-62-9 (3S,7aS)-methyl 3-tert-butyl-6-methyl-5-oxo-7-(trifluoromethylsulfonyloxy)-1,3,5,7a-tetrahydropyrrolo[1,2-c]oxazole-7a-carboxylate 
• 108-24-7 acetic anhydride 
• 1352405-95-8 (3R,3aS,4S,6aS)-4-{(2R,3R)-4-(benzyloxy)-2-methyl-3-[triethylsilyloxy]butyl}-3a-hydroxy-3-methyl-6a{triethylsilyloxymethyl}dihydro-1H-furo[3,4-b]pyrrole-2,6(3H,4H)-dione 
• 1352405-91-4 (3R,3aS,4S,6aS)-4-[(2R,3R)-4-(benzyloxy)-3-hydroxy-2-methylbutyl]-3a-hydroxy-6a-(hydroxymethyl)-3-methyldihydro-1H-furo[3,4-b]pyrrole-2,6(3H,4H)-dione 
• 1352405-70-9 (3S,6R,6aS,7S,9aS)-7-[(2R,3R)-4-(benzyloxy)-3-{[tert-butyl(dimethyl)silyl]oxy}-2-methylbutyl]-3-tert-butyl-6a-hydroxy-6-methyldihydrofuro[3',4':2,3]pyrrolo[1,2-c][1,3]oxazole-5,9(6H)-dione 
• 1352405-89-0 (3S,6S,6aS,7S,9aS)-7-[(2R,3R)-4-(benzyloxy)-3-{[tert-butyl(dimethyl)silyl]oxy}-2-methylbutyl]-3-tert-butyl-6a-hydroxy-6-methyldihydrofuro[3',4':2,3]pyrrolo[1,2-c][1,3]oxazole-5,9(6H)-dione 
• 1352405-59-4 (3S,6S,7aR,E)-methyl 7-((3R,4R)-5-(benzyloxy)-4-(tert-butyldimethylsilyloxy)-3-methylpentylidene)-3-tert-butyl-6-methyl-5-oxohexahydropyrrolo[1,2-c]oxazole-7a-carboxylate 
• 1352405-87-8 (3S,7aR)-methyl 7-((3R,4R)-5-(benzyloxy)-4-(tert-butyldimethylsilyloxy)-3-methylpentyl)-3-tert-butyl-6-methyl-5-oxo-1,3,5,7a-tetrahydropyrrolo[1,2-c]oxazole-7a-carboxylate 
• 1352405-85-6 (3S,7aR)-methyl 7-((3R,4R)-5-(benzyloxy)-4-hydroxy-3-methylpentyl)-3-tert-butyl-6-methyl-5-oxo-1,3,5,7a-tetrahydropyrrolo[1,2-c]oxazole-7a-carboxylate 
• 1352405-72-1 C₁₃H₁₉NO₅ 
• 1352405-61-8 (3S,7aR)-methyl 7-((3R,4R,1E)-5-(benzyloxy)-4-hydroxy-3-methylpent-1-enyl)-3-tert-butyl-6-methyl-5-oxo-1,3,5,7a-tetrahydropyrrolo[1,2-c]oxazole-7a-carboxylate 
• 1352405-63-0 (2R,3R)-1-(menzyloxy)-3-methyl-5-(tri-n-butylstannyl)-4-penten-2-ol 

Downstream Products

• 1352406-10-0 ((3R,3aS,4S,6aS)-4-((2R,3R)-3-(ethanoyloxy)-4-hydroxy-2-methylbutyl)-3a-hydroxy-1,3-dimethyl-2,6-dioxohexahydro-1H-furo[3,4-b]pyrrol-6a-yl)methyl ethanoate 

Relevant articles and documents

Formal synthesis of (+)-neooxazolomycin via a Stille cross-coupling/ deconjugation route

A formal synthesis of neooxazolomycin is described via the preparation of Kende's key intermediate in a longest linear sequence of 23 steps. This work is founded upon the union of three fragments: Moloney's lactam-derived triflate, a vinyl stannane and a