1352406-27-9

Basic information

• Product Name: (1R,2S,3R,5R)-5-azido-3-O-benzyloxy-2-O-p-methoxybenzyloxy-1-O-triisopropylsilyloxycycloheptane
• Synonyms: (1R,2S,3R,5R)-5-azido-3-O-benzyloxy-2-O-p-methoxybenzyloxy-1-O-triisopropylsilyloxycycloheptane
• CAS NO: 1352406-27-9
• Molecular Weight: 553.817
• Mol File: 1352406-27-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2S,3R,5R)-5-azido-3-O-benzyloxy-2-O-p-methoxybenzyloxy-1-O-triisopropylsilyloxycycloheptane(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,3R,5R)-5-azido-3-O-benzyloxy-2-O-p-methoxybenzyloxy-1-O-triisopropylsilyloxycycloheptane(1352406-27-9)
• EPA Substance Registry System: (1R,2S,3R,5R)-5-azido-3-O-benzyloxy-2-O-p-methoxybenzyloxy-1-O-triisopropylsilyloxycycloheptane(1352406-27-9)

Safety Data

• Hazardous Substances Data: 1352406-27-9(Hazardous Substances Data)

Downstream Products

• 1352406-28-0 (1R,2R,3R,5R)-5-azido-3-O-benzyloxy-2-O-p-methoxybenzyloxycycloheptan-1-ol 
• 1352406-29-1 (2S,3R,5R)-5-azido-3-O-benzyloxy-2-O-p-methoxybenzyloxycycloheptanone 
• 1352406-30-4 (1R,2S,3R,5R)-3-O-benzyloxy-2-O-p-methoxybenzyloxy-8-azabicyclo[3.2.1]octane-1-ol 
• 131580-36-4 (1R,2S,3R,5R)-8-azabicyclo[3.2.1]octane-1,2,3-triol 

Relevant articles and documents

Chiral pool synthesis of calystegine A3 from 2-deoxyglucose via a Brown allylation

Calystegine A3 is a naturally occurring nortropane iminosugar of which there previously have been three total syntheses. Inspired by our previous work we here report on a fourth approach using 17 steps from 2-deoxy-d-glucose applying a diastereoselective allylation protocol.