1352626-70-0Relevant articles and documents
Oxidative addition of boron trifluoride to a transition metal
Bauer, Juergen,Braunschweig, Holger,Kraft, Katharina,Radacki, Krzysztof
, p. 10457 - 10460 (2011)
A difficult break-up: Boron trifluoride was activated by oxidative addition to the transition-metal complex [(Cy3P)2Pt]. The product of this addition, trans-[(Cy3P)2Pt(BF2) (FBF3)], was characterized by NMR spectroscopy and crystal structure determination. Furthermore, the degradation product trans-[(Cy 3P)2Pt(H)(FBF3)] and the stable derivative trans-[(Cy3P)2Pt(BF2)(Cl)] were fully characterized. Copyright