1352633-94-3

Basic information

• Product Name: [ruthenium(NH2C2H4P(C6H5)2)(η3-allyl)](BF4)
• CAS NO: 1352633-94-3
• Molecular Weight: 687.47
• Mol File: 1352633-94-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [ruthenium(NH2C2H4P(C6H5)2)(η3-allyl)](BF4)(CAS DataBase Reference)
• NIST Chemistry Reference: [ruthenium(NH2C2H4P(C6H5)2)(η3-allyl)](BF4)(1352633-94-3)
• EPA Substance Registry System: [ruthenium(NH2C2H4P(C6H5)2)(η3-allyl)](BF4)(1352633-94-3)

Safety Data

• Hazardous Substances Data: 1352633-94-3(Hazardous Substances Data)

Usage

Reaction

A highly active catalyst for the hydrogenation of amides to alcohols and amines. Catalyst used for the hydrogenation of functionalized amides under basic and neutral conditions.

Upstream product

• 4848-43-5 (2-aminoethyl)diphenylphosphane 

Relevant articles and documents

A highly active catalyst for the hydrogenation of amides to alcohols and amines

Amide-zing: The reaction between 2 equivalents of Ph2P(CH 2)2NH2 and cis-[Ru(CH3CN) 2(η3-C3H5)(cod)]BF4 (cod=1,5-cyclooctadiene) forms a highly active catalyst precursor for the selective hydrogenation of amides. The reaction proceeds with excellent atom economy, yield, and turnover numbers (TONs) under moderate reaction conditions. The technology offers a greener, practical approach to the use of metal hydride reagents commonly employed in both academia and industry. Copyright