1352644-72-4Relevant academic research and scientific papers
Benzylation of Imines with Activated Boronate Nucleophiles
Hollerbach, Michael R.,Hayes, Jacob C.,Barker, Timothy J.
, p. 1646 - 1648 (2019)
Benzylation reactions of N-tosylimines and N-tert-butanesulfinyl imines using benzylboronic acid pinacol ester are reported. s-Butyllithium was used to activate the boronic ester, rendering it nucleophilic. The reaction was compatible with electronically
Tetrabenzylhafnium as a new organometallic reagent for imine addition resulting in α-branched amines
Mei, Haibo,Ji, Xiaoyun,Han, Jianlin,Pan, Yi
supporting information; experimental part, p. 5783 - 5786 (2011/11/06)
Tetrabenzylhafnium has been explored as a new organometallic reagent for the imine addition reaction. This reagent tolerates a wide scope of imines, affording α-branched amines in excellent yields without the use of any additive or catalyst. This new reag
