1352717-86-2

Basic information

• Product Name: 2,3,4-tri-O-benzyl-β-L-arabinopyranosyl chloride
• CAS NO: 1352717-86-2
• Molecular Weight: 438.951
• Mol File: 1352717-86-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3,4-tri-O-benzyl-β-L-arabinopyranosyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4-tri-O-benzyl-β-L-arabinopyranosyl chloride(1352717-86-2)
• EPA Substance Registry System: 2,3,4-tri-O-benzyl-β-L-arabinopyranosyl chloride(1352717-86-2)

Safety Data

• Hazardous Substances Data: 1352717-86-2(Hazardous Substances Data)

Upstream product

• 52544-91-9 phenyl 2,3,4-tri-O-acetyl-1-thio-α-L-arabinopyranoside 
• 1352718-30-9 C₁₁H₁₄O₄S 
• 1352718-31-0 C₃₂H₃₂O₄S 
• 1233-03-0 1,2,3,4-tetra-O-acetyl-L-arabinopyranose 

Downstream Products

• 1352718-46-7 methyl 2,3-di-O-methyl-4-O-(2,3,4-tri-O-benzyl-α-L-arabinopyranosyl)-α-D-glucopyranoside 
• 1352718-47-8 methyl 2,3-di-O-methyl-6-O-(2,3,4-tri-O-benzyl-α-L-arabinopyranosyl)-α-D-glucopyranoside 

Relevant articles and documents

New method for regioselective glycosylation employing saccharide oxyanions

As an alternative concept for glycosylation, the prior activation of acceptor hydroxy groups for selective glycosidic bond formation, was investigated to give complex oligosaccharides. Oxyanions obtained from partially protected saccharides were glycosylated by employing glycopyranosyl halides, and the regiochemical results were studied. Initially, partially methylated methyl-α-D-glucopyranosides were used as a model system to study the underlying mechanistic principles of base-promoted glycosylation. High regioselectivities and stereospecific glycosidic bond formations were achieved, and the scope of the methodology was extended with different perbenzylated glycosyl donors.