1352726-24-9

Basic information

• Product Name: 2-Bromo-1,3,5-tricyclopentylbenzene
• Synonyms: 1-Bromo-2,4,6-tricyclopentylbenzene;2,4,6-Tricyclopentylbromobenzene;2,4,6-Tricyclopentylphenyl bromide;2-Bromo-1,3,5-tricyclopentylbenzene
• CAS NO: 1352726-24-9
• Molecular Formula: C₂₁H₂₉Br
• Molecular Weight: 361.35896
• Mol File: 1352726-24-9.mol
• Article Data: 5

Chemical Properties

• Flash Point: 47℃
• Appearance: /
• Density: 1.183 g/mL at 25 °C
• Storage Temp.: ?70°C
• CAS DataBase Reference: 2-Bromo-1,3,5-tricyclopentylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Bromo-1,3,5-tricyclopentylbenzene(1352726-24-9)
• EPA Substance Registry System: 2-Bromo-1,3,5-tricyclopentylbenzene(1352726-24-9)

Safety Data

• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 26-36
• RIDADR: UN 1993C 3 / PGIII
• Hazardous Substances Data: 1352726-24-9(Hazardous Substances Data)

Upstream product

• 137-43-9 Cyclopentyl bromide 
• 626-39-1 1,3,5-trisbromobenzene 
• 71-43-2 benzene 

Relevant articles and documents

An Alternative Synthesis of Cycloalkyl-Substituted CPA Catalysts and Application in Asymmetric Protonation Reactions**

An alternative synthesis of cycloalkyl-substituted CPA catalysts is reported. A Negishi coupling offers improved yields and purity of the necessary 1,3,5-tri(cycloalkyl)benzenes. Limitations in the use of commercial organozinc reagents have been identifie

Enantioselective organocatalytic fluorination-induced Wagner-Meerwein rearrangement

Cracked under strain: Strained allylic cyclobutanols and cyclopropanols readily undergo a ring expansion described by the title rearrangement. This reaction is promoted by catalytic amounts of 1 and displays high tolerance with respect to the substrate scope. The corresponding β-fluoro spiroketone products are isolated in high yields and with excellent stereoselectivities. EDG=electron-donating group, EWG=electron-withdrawing group. Copyright

A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions

A new bulky biarylphosphine ligand (L8) has been developed that allows the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions than previously possible. A direct correlation between the size of the ligand substituents in the 2′, 4′, and 6′ positions of the nonphosphine containing ring and the reactivity of the derived catalyst system was observed. Specifically, the rate of coupling increased with the size of these substituents.