1352801-41-2

Upstream product

• 35657-34-2 (O-pivaloylhydroxyl)amine 
• 1079-02-3 benzoic acid-2,3,4,5,6-d5 
• 1293990-73-4 O-pivaloylhydroxylamine trifluoromethanesulfonate salt 
• 98-73-7 4-(1,1-dimethylethyl)benzoic acid 
• 1710-98-1 p-tert-butyl benzoyl chloride 

Downstream Products

• 1352801-57-0 4-(tert-butyl)-2-morpholin-4-yl-N-(pivaloyloxy)benzamide 
• 1400655-66-4 (Z)-6-(tert-butyl)-4-(cyclohexylmethylene)-3,4-dihydroisoquinolin-1(2H)-one 

Relevant academic research and scientific papers

Mild rhodium(III)-catalyzed C-H activation and intermolecular annulation with allenes

All(enes) great! A novel RhIII-catalyzed oxidative coupling with allenes under mild conditions provides heterocycles with exocyclic double bonds. This reaction features low catalyst loadings, high regio- and stereoselectivity, and excellent substrate scope. The products were derivatized and preliminary mechanistic studies were conducted. Copyright

Rh[III]-catalyzed direct C-H amination using N -chloroamines at room temperature

An efficient Rh(III)-catalyzed direct C-H amination of N-pivaloyloxy benzamides with N-chloroamines proceeding at room temperature was achieved. The versatile directing group allows for selective mono- and diamination and can be readily converted to give valuable benzamide or aminoaniline derivatives. Mechanistic studies have been carried out to elucidate the reaction pathway.