1352807-40-9

Upstream product

• 1352807-36-3 1-(2,6-diisopropylphenyl)-3-methyl-4-phenyl-1H-1,2,3-triazol-3-ium tetrafluoroborate 
• 7558-02-3 potassium bromide 
• 20667-12-3 silver(l) oxide 

Downstream Products

• 1352807-45-4 [RhBr(COD)(C₆H₅C₂N₃(CH₃)(2,6-diisopropylphenyl))] 

Relevant academic research and scientific papers

Synthesis and structure of silver and rhodium 1,2,3-triazol-5-ylidene mesoionic carbene complexes

New mono- and bidentate 1,2,3-triazol-5-ylidene mesoionic carbene (MIC) ligands have been synthesized and reacted with silver oxide, forming cationic 1:2 and 2:2 Ag:MIC ([AgL2]Br and [Ag2L2] [Ag2Br4]) complexes, respectively. These complexes have been isolated and characterized. They were further found to be potent transmetalation agents toward rhodium, resulting in the preparation of mono- and bimetallic rhodium complexes. The reaction of the 2:2 Ag:L complex with [Rh(COD)2]BF4 results in the first reported example of a cationic bimetallic rhodium MIC complex. This complex was fully characterized, and its X-ray structure is reported. Interestingly, this complex exhibits various secondary noncovalent interactions in the solid state of the general type C-HX, where X = F, Cl.