1352816-01-3Relevant academic research and scientific papers
Total synthesis of (+)-daphmanidin e
Weiss, Matthias E.,Carreira, Erick M.
, p. 11501 - 11505 (2012/01/12)
From ring to ring: The first total synthesis of (+)-daphmanidinE features rapid access to an enantiomerically pure bicyclo[2.2.2]octadione and elaboration around its periphery through the implementation of two Claisen rearrangements, the use of a copper/peptide complex for reagent-controlled stereoselective conjugate addition, a diastereoselective hydroboration, and a cobalt-catalyzed alkyl-Heck cyclization.
