1352951-80-4

Basic information

• Product Name: C₂₇H₃₈Br₂N₂Si
• Synonyms: C₂₇H₃₈Br₂N₂Si
• CAS NO: 1352951-80-4
• Molecular Weight: 578.506
• Mol File: 1352951-80-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₂₇H₃₈Br₂N₂Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₃₈Br₂N₂Si(1352951-80-4)
• EPA Substance Registry System: C₂₇H₃₈Br₂N₂Si(1352951-80-4)

Safety Data

• Hazardous Substances Data: 1352951-80-4(Hazardous Substances Data)

Upstream product

• 1352951-79-1 Br^(1-)*C₂₇H₃₈Br₃N₂Si⁽¹⁺⁾ 
• 258278-28-3 1,3-bis(2,6-diisopropylphenyl)dihydroimidazol-2-ylidene 
• 1064078-46-1 2,6-bis(2,4,6-trimethylphenyl)phenyl isocyanide 

Relevant articles and documents

Erratum: (NHC)Si═C═N-R: A Two-Coordinated Si0-Isocyanide Compound as Si(NHC) Transfer Reagent (Journal of the American Chemical Society (2021) 143: 36 (14780?14794) DOI: 10.1021/jacs.1c0662)

The entry of the compound 3[B(ArF)4](C6H5F)·0.5- (C5H12) in Table S6 in the Supporting Information has been corrected as the boron atom of the borate anion was mistakenly refined as carbon. The correction led to a slight improvement of the quality parameters as well as some minor changes in formula weight and the calculated density. All relevant bonding parameters and all conclusions remain the same. The paper is unchanged, and the deposited data in the CCDC database had been corrected accordingly.

Chromium-silicon multiple bonds: The chemistry of terminal N-heterocyclic-carbene-stabilized halosilylidyne ligands

An efficient method for the synthesis of the first N-heterocyclic carbene (NHC)-stabilized halosilylidyne complexes is reported that starts from SiBr 4. In the first step, SiBr4 was treated with one equivalent of the N-heterocyclic c