135299-29-5Relevant academic research and scientific papers
Organocatalytic chemoselective asymmetric N-allylic alkylation of enamides
Huang, Ji-Rong,Cui, Hai-Lei,Lei, Jie,Sun, Xun-Hao,Chen, Ying-Chun
supporting information; experimental part, p. 4784 - 4786 (2011/06/20)
The first Lewis base-catalysed chemoselective asymmetric N-allylic alkylation of enamides with Morita-Baylis-Hillman carbonates has been developed, which affords multifunctional products in moderate to high enantioselectivity (up to 92% ee). The Royal Soc
Synthesis of methyl 9-phenyl-7H-benzocycloheptene-6-carboxylates from Baylis-Hillman adducts: Use of intramolecular Friedel-Crafts alkenylation reaction
Gowrisankar, Saravanan,Lee, Ka Young,Lee, Chang Gon,Kim, Jae Nyoung
, p. 6141 - 6146 (2007/10/03)
We developed a facile synthetic method for 9-phenyl-7H-benzocycloheptene derivatives from the Baylis-Hillman adducts. Our method involved intramolecular Friedel-Crafts alkenylation reaction of triple bond-tethered methyl cinnamates.
Reaction of carbanions with methyl 3-acetoxy-2-methylenepropanoates in solid-liquid medium. Application to the synthesis of γ- et δ-lactones
Bauchat, P.,Rouille, E. Le,Foucaud, A.
, p. 267 - 271 (2007/10/02)
Carbanions generated by treating a β-diketone, the methyl cyanoacetate or a nitroalkane with potassium carbonate or potassium fluoride on alumina, without solvent, react with methyl 3-acetoxy-2-methylenepropanoates to give Michael adducts with allylic rea
