1353017-52-3Relevant academic research and scientific papers
Divergent outcomes of carbene transfer reactions from dirhodium- and copper-based catalysts separately or in combination
Xu, Xinfang,Hu, Wen-Hao,Zavalij, Peter Y.,Doyle, Michael P.
, p. 11152 - 11155 (2012/02/03)
Divergent catalysis: The use of copper and rhodium catalysts separately or in combination directs reactions between vinyldiazoacetates 1 and cinnamaldehydes 2 from formal [4+3] cycloaddition (epoxidation followed by Cope rearrangement), to intramolecular cyclopropanation, to Mukaiyama-aldol reactions. The reactions proceed selectively and in high yield. Copyright
