1353044-30-0Relevant academic research and scientific papers
Copper-catalyzed 1,2-addition of nucleophilic silicon to aldehydes: Mechanistic insight and catalytic systems
Kleeberg, Christian,Feldmann, Evgenia,Hartmann, Eduard,Vyas, Devendra J.,Oestreich, Martin
, p. 13538 - 13543 (2011)
Activation of the Si-B inter-element bond with copper(I) alkoxides produces copper-based silicon nucleophiles that react readily with aldehydes to yield α-silyl alcohols (that is, α-hydroxysilanes) after hydrolysis. Two independent protocols were develope
