135347-79-4Relevant academic research and scientific papers
Cycloaddition of Acylnitroso Compounds and Nitrosobenzene with the Pyrrolidine Dienamine of Pummerer's Ketone: X-Ray Crystal Structure of a Bridged 1,2-Oxazine Derivative
Freer, Andrew A.,Islam, Md. Azizul,Kirby, Gordon W.,Mahajan, Mohinder P.
, p. 1001 - 1007 (2007/10/02)
When the pyrrolidine dienamine 2 of Pummerer's ketone 1 was treated with nitrosocarbonylmethane 4, generated in situ by periodate oxidation of acetohydroxamic acid, the major product was a bridged 1,2-oxazine, shown to have the structure 10 by X-ray cryst
REACTIONS OF THE PYRROLIDINE DIENAMINE OF PUMMERER'S KETONE WITH NITROSOCARBONYLMETHANE
Freer, Andrew A.,Islam, Md. Azizul,Kirby, Gordon W.,Mahajan, Mohinder P.
, p. 147 - 150 (2007/10/02)
The pyrrolidine dienamine (2) of Pummerer's ketone (1) reacts with the dienophile nitrosylcarbonylmethane to give a bridged oxazine (9).The structure (9), incorporating 2 mol equiv. of the nitroso compound with reductive loss of 1 oxygen atom, has been de
