135351-56-3

Upstream product

• 77188-80-8 (3S)-5-(4-Methoxybenzocyclobuten-1-yl)-2-methylpent-1-en-3-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 135351-52-9 (2R,3S)-3-[2-(3-Methoxy-bicyclo[4.2.0]octa-1,3,5-trien-7-yl)-ethyl]-2-methyl-oxiran-2-ol 
• 135351-53-0 Methanesulfonic acid (2S,3S)-3-[2-(3-methoxy-bicyclo[4.2.0]octa-1,3,5-trien-7-yl)-ethyl]-2-methyl-oxiranyl ester 
• 135351-51-8 (E)-5-(3-Methoxy-bicyclo[4.2.0]octa-1,3,5-trien-7-yl)-pent-2-en-2-ol 
• 140138-26-7 5-(4-Methoxybenzocyclobuten-1-yl)-2-methylpent-2-en-1-ol 
• 135351-50-7 Ethyl 5-(4-methoxybenzocyclobuten-1-yl)-2-methylpent-2-enoate 
• 80251-97-4 3-(1,2-dihydro-4-methoxybenzocyclobuten-1-yl)propanal 
• 140138-27-8 (2S,3S)-2,3-Epoxy-5-(4-methoxybenzocyclobuten-1-yl)-2-methylpentan-1-ol 

Downstream Products

• 135351-61-0 tert-Butyl-((3R,3aR,9bR)-7-methoxy-3a-methyl-2,3,3a,4,5,9b-hexahydro-1H-cyclopenta[a]naphthalen-3-yloxy)-diphenyl-silane 
• 135351-61-0 tert-Butyl-((S)-7-methoxy-3a-methyl-2,3,3a,4,5,9b-hexahydro-1H-cyclopenta[a]naphthalen-3-yloxy)-diphenyl-silane 

Relevant academic research and scientific papers

A Novel Chiral Approach to trans-3a,4,5,9b-Tetrahydro-1H-benzindene

Enantioselectivity in the thermolysis of the optically active alkenic benzocyclobutenes 9a-g has been studied, resulting in the development of a novel and efficient route to chiral trans-3a,4,5,9b-tetrahydro-1H-benzindenes 10 and 11.

A Novel Approach to Optically Active trans-Benzoperhydroindan (2,3,3a,3b,4,5-Hexahydro-1H-benzindene)

Optically active trans-benzperhydroindan 1 and its enantiomer have been synthesised by thermolysis of the optically active alkenic benzocyclobutene 10 as a key process.