135359-27-2Relevant academic research and scientific papers
Simple synthesis of optically active 2-fluoropropanoic acid and analogs of high enantiomeric purity
Fritz-Langhals, Elke,Schuetz, Gabi
, p. 293 - 296 (2007/10/02)
A very simple synthesis of optically active 2-fluoropropanoic acid 1 (R=CH3, R′=H) and analogs of high enantiomeric purity was developed using the sulfonates 2 of the corresponding optically active 2-hydroxycarboxylic esters and potassium fluor
The hydrogenation of fluoroolefins
Allmendinger,Dandois,Walliser
, p. 2735 - 2736 (2007/10/02)
Palladium catalysts are found to selectively hydrogenate fluoroolefins without hydrogenolytic cleavage of the carbon-fluorine bond. Since a large number of methods are available for the preparation of unsaturated organofluoro compounds this constitutes a general synthetic route to sp3-fluorinated molecules.
