135366-63-1

Basic information

• Product Name: ethyl α-acetyl-α-hydroxy-benzenepropanoate
• Synonyms: ethyl α-acetyl-α-hydroxy-benzenepropanoate
• CAS NO: 135366-63-1
• Molecular Weight: 236.268
• Mol File: 135366-63-1.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: ethyl α-acetyl-α-hydroxy-benzenepropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl α-acetyl-α-hydroxy-benzenepropanoate(135366-63-1)
• EPA Substance Registry System: ethyl α-acetyl-α-hydroxy-benzenepropanoate(135366-63-1)

Safety Data

• Hazardous Substances Data: 135366-63-1(Hazardous Substances Data)

Upstream product

• 620-79-1 Ethyl 2-benzylacetoacetate 
• 34867-86-2 2,3-dioxaspiro[4.4]nonane-1,4-dione 

Relevant articles and documents

Mild air-oxidation of 1,3-dicarbonyl compounds with cesium salts: Novel α-hydroxylation accompanied by partial hydrolysis of malonate derivatives

1,3-Dicarbonyl compounds (1) were efficiently oxygenated at the α-position with cesium salts, such as CsF or Cs2CO3 (0.1 Meq) in DMF at room temperature. Reaction of malonate derivatives (1a, b) with excess amount (2 Meq) of Cs2

Lanthanide-catalyzed oxyfunctionalization of 1,3-diketones, acetoacetic esters, and malonates by oxidative C-O coupling with malonyl peroxides

The lanthanide-catalyzed oxidative C-O coupling of 1,3-dicarbonyl compounds with diacyl peroxides, specifically the cyclic malonyl peroxides, has been developed. An important feature of this new reaction concerns the advantageous role of the peroxide acti

I2-catalyzed direct α-hydroxylation of β-dicarbonyl compounds with atmospheric oxygen under photoirradiation

An I2-catalyzed hydroxylation of β-dicarbonyl moieties using air as the oxidant under photoirradiation has been developed for the easy preparation of α-hydroxy-β-dicarbonyl compounds. The transformation was completed with only 1 mol % of I2. With α-unsubstituted malonates, the hydroxylated dimerization product was afforded as the predominant product along with a minor product, α,α-dihydroxyl malonate.

Chiral broensted acid-catalyzed enantioselective α- hydroxylation of β-dicarbonyl compounds

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