1353674-91-5Relevant academic research and scientific papers
Rhodium-catalyzed asymmetric arylation of N -(tert -butanesulfinyl)imines with sodium tetraarylborates
Reddy, Leleti Rajender,Gupta, Aditya P.,Villhauer, Eric,Liu, Yugang
experimental part, p. 1095 - 1100 (2012/03/12)
A diastereoselective rhodium-catalyzed arylation of N-(tert-butanesulfinyl) imines with sodium tetraarylborates is described. This method is general for constructing various chiral α-branched amines and 2-substituted pyrrolidines with high diastereoselectivity. A practical asymmetric approach to access chiral amines has been developed involving the use of air-stable Rh catalysts and reagents and in the absence of an external ligand.
