1353844-82-2Relevant academic research and scientific papers
Bonding and reactivity in the electronically unsaturated hydrogen-bridged dimer [Ru3(CO)8(μ3-CMe)(μ-H) 2(μ3-H)]2
Adams, Richard D.,Kan, Yuwei,Zhang, Qiang,Hall, Michael B.,Trufan, Eszter
, p. 50 - 53 (2012)
The electronically unsaturated complex [Ru3(CO) 8-(μ3-CMe)(μ-H)2(μ3-H)] 2 (1), viewed as a dimer of the 46-electron fragment Ru 3(CO)8(μ3-CMe)(μ-H)3, is held together by delocalized bonding involving two triply bridging hydride ligands. Compound 1 exhibits a dynamic activity in solution that equilibrates two of the three types of hydride ligands. Compound 1 reacts with 1,1- bis(diphenylphosphino) methane to form the macrocyclic complex [Ru 3(CO)7-(μ3-CMe)(μ-H)3] 2(μ-dppm)2 (3).
