135394-60-4

Upstream product

• 56174-66-4 2-(N,N-dimethylaminomethyl)phenyllithium 
• 143504-44-3 hexakis[2-(dimethylaminomethyl)phenyl]cyclotrisilane 
• 135394-59-1 [2-(dimethylaminomethyl)phenyl]trichlorosilane 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 174501-25-8 1,2-dichloro-1,1,2,2-tetrakis[2-(dimethylaminomethyl)phenyl]disilane 

Downstream Products

• 143504-47-6 bis<2-(dimethylaminomethyl)phenyl>silane 
• 143504-46-5 1,1,2,2-tetrakis[2-(dimethylaminomethyl)phenyl]disilane 
• 153686-73-8 Tris<2-(dimethylaminomethyl)phenyl>silan 
• 143504-44-3 hexakis[2-(dimethylaminomethyl)phenyl]cyclotrisilane 
• 174501-25-8 1,2-dichloro-1,1,2,2-tetrakis[2-(dimethylaminomethyl)phenyl]disilane 
• 135394-62-6 Cr(CO)5Si(C₆H₄CH₂N(CH₃)2)2 
• 148569-73-7 {2-{{dimethyl(trifluoroboranyl)amino}methyl}phenyl}{2-{(dimethylamino)methyl}phenyl}silanediylchromium⁽⁰⁾ pentacarbonyl 
• 143504-45-4 1,1,3,3-tetrakis<2-(dimethylaminomethyl)phenyl>-1,3-dihydroxydisiloxane 

Relevant academic research and scientific papers

Synthesis of di- and trisilanes with potentially chelating substituents

Silylenes 2 or 4, generated by thermolysis of cyclotrisilanes 1 and 3, were inserted into the Si-Cl or Si-H bonds of monosilanes to yield a variety of disilanes, which can be further functionalized subsequently. In a few cases, trisilanes are accessible by the reaction of 1 with disilanes. The reaction of a metalated silane with a chlorosilane is an alternative method for the formation of Si-Si bonds, which turned out to be especially useful for the synthesis of bulkily substituted disilanes. Some of the new dichlorodiand trisilanes themselves serve as thermal precursors of silylenes 2 or 4, the extrusion of which can be catalyzed by 1 or 3 in certain cases.