135397-27-2Relevant academic research and scientific papers
Synthesis of Enantioenriched α-Hydroxy-α-allenylacetic Acids by Wittig Rearrangement of (Propargyloxy)acetates
Marshall, James A.,Wang, Xiao-jun
, p. 4913 - 4918 (2007/10/02)
Optically active (R)-(propargyloxy)acetic esters 5, available in ca. 90 percent ee through reduction of alkynones 2 with Chirald-LiAlH4 followed by alkylation with chloroacetic acid and esterification with CH2N2, undergo highly stereoselective rearr
