135441-93-9Relevant academic research and scientific papers
STEREOSPECIFIC REDUCTION OF DIASTEREOMERICALLY PURE MENTHYL PHOSPHINATES: A NEW ROUTE TO OPTICALLY ACTIVE PHOSPHINE OXIDES
Koide, Yasuhiro,Sakamoto, Atsushi,Imamoto, Tsuneo
, p. 3375 - 3376 (2007/10/02)
Diastereomerically pure menthyl phosphinates are stereospecifically reduced by lithium 4,4'-di-tert-butylbiphenylide.Subsequent treatment with alkyl halides affords phosphine oxides with high optical purity.
