1354577-36-8

Basic information

• Product Name: (2R,3S)-benzoic acid 2-(tert-butyldimethylsilanyloxymethyl)-3,4-dihydro-2H-pyran-3-yl ester
• Synonyms: (2R,3S)-benzoic acid 2-(tert-butyldimethylsilanyloxymethyl)-3,4-dihydro-2H-pyran-3-yl ester
• CAS NO: 1354577-36-8
• Molecular Weight: 348.514
• Mol File: 1354577-36-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S)-benzoic acid 2-(tert-butyldimethylsilanyloxymethyl)-3,4-dihydro-2H-pyran-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S)-benzoic acid 2-(tert-butyldimethylsilanyloxymethyl)-3,4-dihydro-2H-pyran-3-yl ester(1354577-36-8)
• EPA Substance Registry System: (2R,3S)-benzoic acid 2-(tert-butyldimethylsilanyloxymethyl)-3,4-dihydro-2H-pyran-3-yl ester(1354577-36-8)

Safety Data

• Hazardous Substances Data: 1354577-36-8(Hazardous Substances Data)

Upstream product

• 136573-59-6 1,5-anhydro-3,4-di-O-benzoyl-6-O-t-butyldimethylsilyl-2-deoxy-D-arabino-hex-1-enitol 

Relevant articles and documents

Sodium borohydride-nickel chloride-methanol catalytic system for regioselective reduction of electron-rich conjugated dienes and reductive cleavage of allyl esters involving π-allylnickel intermediates

The regioslective reduction of electron-rich dienes to monoolefins and the reductive cleavage of allyl esters were fulfilled by employing a sodium borohydride-nickel chloride-methanol catalytic system with exceedingly simple manipulations and high functional group tolerability. Both of the reductive reactions may involve π-allylnickel intermediates generated from fresh nickel boride. Copyright