1354644-23-7

Basic information

• Product Name: N-(2-allyloxybenzylidene)-2-methylbenzenamine
• Synonyms: N-(2-allyloxybenzylidene)-2-methylbenzenamine
• CAS NO: 1354644-23-7
• Molecular Weight: 251.328
• Mol File: 1354644-23-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(2-allyloxybenzylidene)-2-methylbenzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-allyloxybenzylidene)-2-methylbenzenamine(1354644-23-7)
• EPA Substance Registry System: N-(2-allyloxybenzylidene)-2-methylbenzenamine(1354644-23-7)

Safety Data

• Hazardous Substances Data: 1354644-23-7(Hazardous Substances Data)

Upstream product

• 28752-82-1 2-(allyloxy)benzaldehyde 
• 95-53-4 o-toluidine 

Downstream Products

• 4749-47-7 2-(1H-indol-2-yl)phenol 
• 3246-73-9 N-salicylidene-o-methylaniline 
• 1745-81-9 o-Allylphenol 

Relevant articles and documents

Gas-phase generation and cyclisation reactions of imidoyl radicals

Some 1,2-diarylimidoyl radicals were generated in the gas-phase by intramolecular radical translocation from ortho-imino-aryloxyl radicals, in turn generated under flash vacuum pyrolysis (FVP) conditions. The imidoyls reacted with XR ortho′-substituents in the N-aryl group to give (in most cases) modest yields of cyclisation products. Depending on the nature of the bridging atom (X), the formation of these products was initiated either by a further hydrogen atom translocation (X = CH2), or by ipso-attack onto the aryl group (R = Ph), or by direct substitution at the heteroatom (X = S). With XR = N(Me)Ph, the major reaction product was probably the result of a competing pathway not involving the corresponding imidoyl.