1354648-71-7

Basic information

• Product Name: C₄₆H₃₈N₄O₄
• Synonyms: C₄₆H₃₈N₄O₄
• CAS NO: 1354648-71-7
• Molecular Weight: 710.832
• Mol File: 1354648-71-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₄₆H₃₈N₄O₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₆H₃₈N₄O₄(1354648-71-7)
• EPA Substance Registry System: C₄₆H₃₈N₄O₄(1354648-71-7)

Safety Data

• Hazardous Substances Data: 1354648-71-7(Hazardous Substances Data)

Upstream product

• 1226-42-2 1,2-bis(4-methoxyphenyl)-1,2-ethanedione 
• 1210-05-5 Biphenyl-2,2'-dicarbaldehyde 

Downstream Products

• 1354648-72-8 C₄₆H₃₆N₄O₄ 

Relevant articles and documents

Unusual negative photochromism via a short-lived imidazolyl radical of 1,1′-binaphthyl-bridged imidazole dimer

We have synthesized a new photochromic compound that exhibits unusual negative photochromism, in which the stable colored species photochemically converts into the metastable colorless species via a short-lived radical. This compound has a 1,1′-binaphthyl moiety bridging the two diphenylimidazole units. Its photochemical properties were investigated by nanosecond laser flash photolysis. The colored species isomerizes to the colorless species upon exposure to visible light and thermally returns to the original colored species within 20 min at room temperature. Moreover, the photodecoloration reaction proceeds via a short-lived radical with a half-life of 9.4 μs in benzene at room temperature. Both the colored and colorless species show the photoinduced homolytic bond cleavage reaction of the C-N bond between the nitrogen atom of the imidazole ring and the carbon atom of the 1-position of the 1,1′-binaphthyl moiety and that of the C-C bond between each of the carbon atoms of the 2-position of the imidazole ring, respectively, followed by their formation by rapid radical coupling.