135490-93-6Relevant academic research and scientific papers
Chemoselective mono halogenation of β-keto-sulfones using potassium halide and hydrogen peroxide; synthesis of halomethyl sulfones and dihalomethyl sulfones
Suryakiran,Prabhakar,Srikanth Reddy,Chinni Mahesh,Rajesh,Venkateswarlu
, p. 877 - 881 (2007/10/03)
The synthesis of α-halo β-keto-sulfones using potassium halide and hydrogen peroxide as a chemoselective mono halogenation reagent and the synthesis of α,α-symmetrical and asymmetrical dihalo β-keto-sulfones and α-halo, α-alkyl and β-keto-sulfones is described. Base induced cleavage of α-halo β-keto-sulfones, α,α-dihalo β-keto-sulfones, and α-halo, α-alkyl β-keto-sulfones afforded the corresponding halomethyl sulfones, dihalomethyl sulfones and haloalkyl sulfones.
A REDOX REACTION OF (DICHLOROIODO)METHYLPHENYL SULFONE
Varella, Evangelia,Varvoglis, Anastasios
, p. 275 - 277 (2007/10/02)
The title compound, PhSO2CH2ICl2, is converted by metal acetates into either (chloro-iodo)methyl phenyl sulfone, PhSO2CHClI, or esters PhSO2CH(OCOR)I.
