1355049-19-2

Basic information

• Product Name: C₁₀H₈BrNO₃
• CAS NO: 1355049-19-2
• Molecular Weight: 270.082
• Mol File: 1355049-19-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₀H₈BrNO₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₀H₈BrNO₃(1355049-19-2)
• EPA Substance Registry System: C₁₀H₈BrNO₃(1355049-19-2)

Safety Data

• Hazardous Substances Data: 1355049-19-2(Hazardous Substances Data)

Upstream product

• 19725-82-7 5-Bromo-2-carboxymethyl-benzoic acid 
• 1355049-16-9 methyl [2-(azidocarbonyl)-4-bromophenyl]acetate 
• 1355049-15-8 5-bromo-2-(2-methoxy-2-oxoethyl)benzoic acid 
• 552333-33-2 7-bromo-1H-isochromene-1,3(4H)-dione 

Downstream Products

• 1355049-21-6 6-bromo-2-hydroxy-N₁,N₃-diphenyl-1H-indole-1,3-dicarboxamide 
• 99365-40-9 6-bromo-2,3-dihydro-1H-indole-2-one 
• 1355049-18-1 methyl {2-[(anilinocarbonyl)amino]-4-bromophenyl}acetate 

Relevant articles and documents

Synthesis of indolin-2-one, isoindolin-1-one, and indole derivatives from homophthalic acid

We hereby report the preparation of indolin-2-one and isoindolin-1-one and their derivatives starting from 2-(carboxymethyl)benzoic acid, which was first regiospecifically converted into the isomeric half esters. Transformation of the acid functionalities to the acyl azides followed by Curtius rearrangement gave the regioisomeric isocyanates. Reaction of the isocyanates with aniline produced urethane derivatives. Intramolecular cyclization provided the target compounds. Georg Thieme Verlag Stuttgart. New York.