1355058-84-2Relevant academic research and scientific papers
Ruthenium-Catalyzed Electrochemical Dehydrogenative Alkyne Annulation
Xu, Fan,Li, Yan-Jie,Huang, Chong,Xu, Hai-Chao
, p. 3820 - 3824 (2018/05/22)
A ruthenium-catalyzed electrochemical dehydrogenative annulation reaction of aniline derivatives and alkynes has been developed for the synthesis of indoles. Electric current is used to recycle the active ruthenium-based catalyst and promote H2 evolution. The electrolysis reaction is operationally convenient as it employs a simple undivided cell, proceeds efficiently in an aqueous solution, and is insensitive to air.
Cationic ruthenium(II) catalysts for oxidative C - H/N - H bond functionalizations of anilines with removable directing group: Synthesis of indoles in water
Ackermann, Lutz,Lygin, Alexander V.
, p. 764 - 767 (2012/04/17)
Cationic ruthenium(II) complexes enabled oxidative C - H bond functionalizations with anilines bearing removable directing groups. The C - H/N - H bond cleavages occurred most efficiently in water as a sustainable solvent and provided general access to va
