1355151-66-4Relevant academic research and scientific papers
Organocatalytic asymmetric wittig reactions: Generation of enantioenriched axially chiral olefins breaking a symmetry plane
Gramigna, Lucia,Duce, Sara,Filippini, Giacomo,Fochi, Mariafrancesca,Franchini, Mauro Comes,Bernardi, Luca
, p. 2745 - 2749 (2011/12/21)
The first catalytic asymmetric Wittig reaction is presented. Hydrogen-bond donors catalyze the [2+2] cycloaddition reaction between stabilized phosphorus ylides and 4-substituted cyclohexanones, breaking their symmetry plane and furnishing axially chiral
