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1355154-07-2

[Rh(κ3-(Ph2PCH2CH2)PPh)(η2-vinyltrimethylsilane)][B(C6H3-3,5-(CF3)2)4] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1355154-07-2 Structure

  • Basic information

    1. Product Name: [Rh(κ3-(Ph2PCH2CH2)PPh)(η2-vinyltrimethylsilane)][B(C6H3-3,5-(CF3)2)4]
    2. Synonyms:
    3. CAS NO:1355154-07-2
    4. Molecular Formula:
    5. Molecular Weight: 1600.92
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1355154-07-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [Rh(κ3-(Ph2PCH2CH2)PPh)(η2-vinyltrimethylsilane)][B(C6H3-3,5-(CF3)2)4](CAS DataBase Reference)
    10. NIST Chemistry Reference: [Rh(κ3-(Ph2PCH2CH2)PPh)(η2-vinyltrimethylsilane)][B(C6H3-3,5-(CF3)2)4](1355154-07-2)
    11. EPA Substance Registry System: [Rh(κ3-(Ph2PCH2CH2)PPh)(η2-vinyltrimethylsilane)][B(C6H3-3,5-(CF3)2)4](1355154-07-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1355154-07-2(Hazardous Substances Data)

1355154-07-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1355154-07-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,5,5,1,5 and 4 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1355154-07:
(9*1)+(8*3)+(7*5)+(6*5)+(5*1)+(4*5)+(3*4)+(2*0)+(1*7)=142
142 % 10 = 2
So 1355154-07-2 is a valid CAS Registry Number.

1355154-07-2Downstream Products

1355154-07-2Relevant articles and documents

Exploring (Ph2PCH2CH2)2E ligand space (E = O, S, PPh) in RhI alkene complexes as potential hydroacylation catalysts

Pike, Sebastian D.,Pawley, Rebekah J.,Chaplin, Adrian B.,Thompson, Amber L.,Hooper, Joel A.,Willis, Michael C.,Weller, Andrew S.

, p. 5558 - 5565 (2011)

The ligands (Ph2PCH2CH2)2E (E = O, S, PPh) have been used to form a variety of RhI cations [Rh{(Ph2PCH2CH2)2E}(alkene)] + (alkene = methyl acrylate, trimethylvinylsilane). Variable-temperature NMR spectroscopy shows that the methyl acrylate ligands undergo a fluxional process on the metal, via a 1-carbonyl intermediate, while the trimethylvinylsilane complexes cannot access this intermediate and do not undergo the same process. Their reactivity in hydroacylation reactions with 1-pentanal have been investigated, and these studies further suggest the important role that a chelating substituent next to the aldehyde might play in productive hydroacylation. A variety of Rh I cations [Rh{(Ph2PCH2CH2) 2E}(alkene)]+ (E = PPh, S, O; alkene = methyl acrylate and trimethylvinylsilane) have been prepared and their fluxional behaviour investigated by variable-temperature NMR spectroscopy. Copyright

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