135522-23-5

Basic information

• Product Name: 2-(ALLYLOXY)-1-NAPHTHALDEHYDE OXIME
• Synonyms: 2-(ALLYLOXY)-1-NAPHTHALDEHYDE OXIME;(E)-N-{[2-(prop-2-en-1-yloxy)naphthalen-1-yl]methylidene}hydroxylamine
• CAS NO: 135522-23-5
• Molecular Formula: C14H13NO2
• Molecular Weight: 227.26
• Mol File: 135522-23-5.mol
• Article Data: 2

Chemical Properties

• Melting Point: 63-64 °C(Solv: hexane (110-54-3); ethyl acetate (141-78-6))
• Boiling Point: 400.8±28.0 °C(Predicted)
• Appearance: /
• Density: 1.08±0.1 g/cm3(Predicted)
• PKA: 10.74±0.30(Predicted)
• CAS DataBase Reference: 2-(ALLYLOXY)-1-NAPHTHALDEHYDE OXIME(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(ALLYLOXY)-1-NAPHTHALDEHYDE OXIME(135522-23-5)
• EPA Substance Registry System: 2-(ALLYLOXY)-1-NAPHTHALDEHYDE OXIME(135522-23-5)

Safety Data

• Hazardous Substances Data: 135522-23-5(Hazardous Substances Data)

Upstream product

• 19530-43-9 2-allyloxy-1-naphthaldehyde 

Relevant articles and documents

Novel synthesis of naphthopyranoisoxazoles and versatile access to naphthopyranoisoxazolines

2-(Alkenyloxy)naphthalene-1-carbaldehyde oximes are oxidized with potassium iodide, iodine and sodium bicarbonate directly to novel naphthopyranoisoxazoles. Naphthopyranoisoxazoles are also prepared from 2-(3-chloroallyloxy)naphthalene-1-carbaldehyde oxime or 2-(alkynyloxy) naphthalene-1-carbaldehyde oximes by oxidation with sodium hypochlorite and triethylamine. The oxidation of 2-(alkenyloxy)naphthalene-1-carbaldehyde oximes with sodium hypochlorite and triethylamine afforded novel naphthopyranoisoxazolines. The former reaction is tentatively proposed to occur via activation of the alkene side chain by means of an iodonium intermediate and either 1,3-dipolar interaction with a nitrile oxide side-group or cyclization with a hydroximic acid iodide side-group. Georg Thieme Verlag Stuttgart.