135523-33-0Relevant academic research and scientific papers
Catalytic Aminomercuration Reactions of 3-Alken-1-ynes: An Improved Method for the Synthesis of 2-Amino-1,3-butadienes and 1-Aza-1,3-butadienes
Barluenga, Jose,Aznar, Fernando,Valdes, Carlos,Cabal, Maria-Paz
, p. 6166 - 6171 (1991)
Catalytic aminomercuration of 3-alken-1-ynes leads to 1-aza-1,3-butadienes and 2-amino-1,3-butadienes.Under appropriate reaction conditions it is possible to prepare these compounds via mercuration of 3-alken-1-ynes in the presence of either aromatic or a
N-H activation vs. C-H activation: Ruthenium-catalysed regioselective hydroamination of alkynes and hydroarylation of an alkene with N-methylaniline
Uchimaru, Yuko
, p. 1133 - 1134 (1999)
Phenylacetylene and its derivatives undergo regioselective insertion into the N-H bond of N-methylaniline in the presence of Ru3(CO)12 catalyst to afford N-methyl-N-(α-styryl)anilines in high yields, whereas styrene reacts with the ortho C-H bond of N-methylaniline giving 2-(1-phenylethyl)-N-methylaniline.
