1355338-87-2Relevant academic research and scientific papers
(Cycloheptadienyl)diphenylphosphine: A versatile hybrid ligand
Massard, Alexandre,Rampazzi, Vincent,Perrier, Arnaud,Bodio, Ewen,Picquet, Michel,Richard, Philippe,Hierso, Jean-Cyrille,Le Gendre, Pierre
, p. 947 - 958 (2012/04/10)
(3,5-Cycloheptadienyl)diphenylphosphine is easily synthesized from the reaction of diphenylphosphine with 1,3,5-cycloheptatriene. This new phosphine-diene has been coordinated as a monodentate P ligand with Pt, Pd, Au, Ni, and Ru; as a bidentate (P, olefin) ligand with Pt and Pd; and as a tridentate (P, diene) ligand with Rh. Fluxional properties of several complexes have been studied via NMR experiments and theoretical consideration.
