135557-36-7Relevant articles and documents
Novel Formation of Isomeric Bicycloheptan-1-ols from Phenyl Vinyl Sulfoxide and the Cyclopentanone Lithium Enolate Generated by Conjugate Addition of Lithiated (E)-But-2-enyldiphenylphosphine Oxide to 2-Methylcyclopent-2-enone
Haynes, Richard K.,Loughlin, Wendy A.,Hambley, Trevor W.
, p. 5785 - 5790 (2007/10/02)
Whereas the title enolate 2 in THF reacts at -10 deg C with 2 equiv of phenyl vinyl sulfone to provide the hydrindanol 9 (9percent), it reacts with 1 equiv of phenyl vinyl sulfoxide to give 7-(phenylsulfinyl)bicycloheptan-1-ol sulfoxides 11 and 12