135579-92-9Relevant academic research and scientific papers
Highly reactive forms of zinc and reagents thereof
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, (2008/06/13)
A novel zerovalent zinc species and an organozinc reagent are disclosed. The zerovalent zinc species is directly produced by reaction of a reducing agent on a zinc salt, preferably Zn(CN)2. The organozinc reagent results from the reaction of the zerovalent zinc species and an organic compound having one or more stable anionic leaving groups. These organozinc reagents include a wide spectrum of functional groups in the organic radical, and are useful in a variety of reactions schemes.
A FACILE METHOD FOR THE PREPARATION OF FUNCTIONALIZED 2,3-DISUBSTITUTED-1,3-BUTADIENES
Zhu, Lishan,Rieke, Reuben D.
, p. 2865 - 2866 (2007/10/02)
Functionalized 2,3-disubstituted-1,3-butadienes were readily prepared by reacting functionalized organozinc compounds with 1,4-dichloro-2-butyne or 1,4-ditosyloxy-2-butyne mediated by Cu(I) salts.
