135583-05-0

Basic information

• Product Name: (Z)-non-6-en-2-one p-tolylsulphonylhydrazone
• Synonyms: (Z)-non-6-en-2-one p-tolylsulphonylhydrazone
• CAS NO: 135583-05-0
• Molecular Weight: 308.445
• Mol File: 135583-05-0.mol

Chemical Properties

• CAS DataBase Reference: (Z)-non-6-en-2-one p-tolylsulphonylhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-non-6-en-2-one p-tolylsulphonylhydrazone(135583-05-0)
• EPA Substance Registry System: (Z)-non-6-en-2-one p-tolylsulphonylhydrazone(135583-05-0)

Safety Data

• Hazardous Substances Data: 135583-05-0(Hazardous Substances Data)

Upstream product

• 135583-01-6 (Z)-3-nitronon-6-en-2-one 
• 98625-88-8 (Z)-1-nitrohept-4-ene 
• 135583-03-8 (Z)-3-nitronon-6-en-2-one p-tolylsulphonylhydrazone 

Downstream Products

• 34019-86-8 (Z)-6-Nonen-2-one 

Relevant articles and documents

New and Convenient Synthesis of (Z)-Heneicos-6-en-11-one, the Douglas Fir Tussock Moth (Orgyia pseudotsugata) Sex Pheromone, and (Z)-Non-6-en-2-one, the Immediate Precursor for the Synthesis of Brevicomin, the Sex Attractant of the Western Pine Beetle Dentroctonus brevicomis

Convenient syntheses of (Z)-heneicos-6-en-11-one and (Z)-non-6-en-2-one were achieved from (Z)-1-nitrodec-4-ene and (Z)-1-nitrohept-4-ene.Solvent-free nitroaldol reaction of (Z)-1-nitro-alkenes 1 with the aldehydes 2 on Amberlyst A-21, followed by in situ oxidation, gave the α-nitro ketones 3.Denitration via p-tolylsulphonylhydrazones and removal of the protecting group gave the title compounds 6a and 6b in 60 and 53 percent overall yield.