135597-77-2Relevant academic research and scientific papers
Exciton Coupling from Dipyrrinone Chromophores
Byun, Young-Seok,Lightner, David A.
, p. 6027 - 6033 (1991)
2,3,7,8-Tetramethyl-(10H)-dipyrrin-1-one-9-carboxylic acid and p-(dimethylamino)benzoic acid are reacted separately with (1R,2R)-cyclohexanediol to form the corresponding diesters (1 and 3, respectively).These diesters exhibit intense bisignate circular dichroism (CD) spectra characteristic of exciton coupling and show a negative exciton chirality: Δεmax408 -122.5, Δεmax360 +95 (1 in CH2Cl2) and Δεmax318 -88.5 , Δεmax292 +41.5 (3 in CH2Cl2).In (CH3)2SO solvent the Cotton effect signs become inverted for the bis(dipyrrinone ester) but remain unchanged for the bis.
LONG-RANGE EXCITON COUPLING FROM DIPYRRINONE CHROMOPHORES
Byun, Young-Seok,Lightner, D. A.
, p. 9759 - 9772 (2007/10/02)
Dipyrrinone chromophores, attached by their acid termini to give (1R,2R)-cyclohexanediol dipropionate and diacetate esters (xanthobilirubinate and nor-xanthobilirubinate, respectively), interact through exciton coupling, as evidenced by intense bisignate
