1356012-67-3

Upstream product

• 75-25-2 Bromoform 
• 57013-04-4 ethene-1,1-diyldicyclohexane 
• 119-60-8 dicyclohexyl ketone 

Downstream Products

• 1356012-23-1 C₂₃H₃₁N 
• 1356012-53-7 3,3'-(3,3-dicyclohexylprop-2-ene-1,1-diyl)bis(1H-indole) 
• 1356012-54-8 3,3'-((3,3-dicyclohexyloxiran-2-yl)methylene)bis(1H-indole) 
• 1356012-49-1 3,3'-(3,3-dicyclohexylprop-2-ene-1,1-diyl)bis(5-methoxy-1H-indole) 
• 1356012-51-5 3,3'-((3,3-dicyclohexyloxiran-2-yl)methylene)bis(5-methoxy-1H-indole) 
• 1356012-55-9 3,3'-(3,3-dicyclohexylprop-2-ene-1,1-diyl)bis(5-fluoro-1H-indole) 
• 1356012-56-0 3,3'-((3,3-dicyclohexyloxiran-2-yl)methylene)bis(5-fluoro-1H-indole) 
• 1356012-43-5 3-(3,3-dicyclohexylallyl)-5-methoxy-1H-indole 
• 1356012-69-5 1-bromo-2,2-dicyclohexylcyclopropane 
• 1356012-59-3 cycloprop-2-ene-1,1-diyldicyclohexane 

Relevant academic research and scientific papers

Rh(II)-Catalyzed [2,3]-Sigmatropic Rearrangement of Sulfur Ylides Derived from Cyclopropenes and Sulfides

(Chemical Equation Presented) A new type of Rh2(OAc)4-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides is reported. A series of cyclopropenes were successfully employed for [2,3]-sigmatropic rearrangement by a reaction with either allylic or propargylic sulfides. Under the optimized conditions, the reaction afforded the products in moderate to excellent yields. In these transformations, the vinyl metal carbenes generated in situ from the cyclopropenes were effectively trapped by sulfides, resulting in the formation of corresponding products upon [2,3]-sigmatropic rearrangements.

Synthesis of Functionalized α-Vinyl Aldehydes from Enaminones

An efficient RhII-catalyzed synthesis of functionalized α-vinyl aldehydes with high E/Z stereoselectivity was developed. The reaction mediates the cyclopropanation of enaminones with vinyl carbenoids that are generated from cyclopropenes in situ to give the aminocyclopropane intermediates. Selective C?C bond cleavage of the cyclopropane intermediates leads to formation of α-vinyl aldehyde derivatives with high E/Z selectivity. This method proceeds at room temperature under very mild reaction conditions and works with a broad substrate scope.

Divergent outcomes of gold(I)-catalyzed indole additions to 3,3-disubstituted cyclopropenes

Depending on the conditions employed, gold(I)-catalyzed addition of indoles to 3,3-disubstituted cyclopropenes can be controlled to yield either 3-(E)-vinylindoles (3) or bis-indolylalkanes (4). If the cyclopropene substituents are sterically bulky, unprecedented gold-catalyzed oxidation under air occurs to yield bis-indolylalkene (5) and epoxide (6) at room temperature.