1356185-75-5

Basic information

• Product Name: (+/-)-1-phenyl-4-methylpentan-3-yl sulfamate
• Synonyms: (+/-)-1-phenyl-4-methylpentan-3-yl sulfamate
• CAS NO: 1356185-75-5
• Molecular Weight: 257.354
• Mol File: 1356185-75-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-1-phenyl-4-methylpentan-3-yl sulfamate(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-1-phenyl-4-methylpentan-3-yl sulfamate(1356185-75-5)
• EPA Substance Registry System: (+/-)-1-phenyl-4-methylpentan-3-yl sulfamate(1356185-75-5)

Safety Data

• Hazardous Substances Data: 1356185-75-5(Hazardous Substances Data)

Upstream product

• 103-63-9 1-phenyl-2-bromoethane 
• 68426-07-3 (+/-)-1-phenyl-5-methylpentan-3-ol 

Relevant articles and documents

Iron-catalyzed intramolecular allylic C-H amination

A highly selective C-H amination reaction under iron catalysis has been developed. This novel system, which employs an inexpensive, nontoxic [Fe IIIPc] catalyst (typically used as an industrial ink additive), displays a strong preference for allylic C-H amination over aziridination and all other C-H bond types (i.e., allylic > benzylic > ethereal > 3° > 2° ? 1°). Moreover, in polyolefinic substrates, the site selectivity can be controlled by the electronic and steric character of the allylic C-H bond. Although this reaction is shown to proceed via a stepwise mechanism, the stereoretentive nature of C-H amination for 3° aliphatic C-H bonds suggests a very rapid radical rebound step.