135625-68-2

Upstream product

• 135649-90-0 (2S,5R)-1-(benzyloxycarbonyl)-2-(hydroxymethyl)-5-methylpyrrolidine 
• 152189-89-4 ((S)-5-Methyl-3,4-dihydro-2H-pyrrol-2-yl)-methanol 
• 4931-66-2 (S)-5-Hydroxy-3,4-dihydro-2H-pyrrole-2-carboxylic acid methyl ester 
• 1134776-91-2 (S)-(1-methylpent-4-enyl)carbamic acid benzyl ester 
• 155835-36-2 (2R,5S)-1-Benzyloxycarbonyl-2-hydroxymethyl-5-methylpyrrolidine 
• 113774-91-7 ((R)-1-Methyl-pent-4-enyl)-carbamic acid benzyl ester 
• 152231-15-7 ((2S,5R)-5-Methyl-pyrrolidin-2-yl)-methanol 
• 152189-90-7 Acetic acid (S)-5-ethoxy-3,4-dihydro-2H-pyrrol-2-ylmethyl ester 
• 109063-57-2 Acetic acid (S)-5-hydroxy-3,4-dihydro-2H-pyrrol-2-ylmethyl ester 
• 17342-08-4 (S)-5-Hydroxymethyl-4,5-dihydro-3H-pyrrol-2-ol 

Downstream Products

• 152231-17-9 (2R,5S)-2-Methyl-5-((E)-3-oxo-dec-1-enyl)-pyrrolidine-1-carboxylic acid benzyl ester 
• 143120-65-4 (Z)-(2S,5R)-1-(benzyloxycarbonyl)-2-(11-(benzyloxy)-3-oxo-1-undecenyl)-5-methylpyrrolidine 
• 143064-43-1 (E)-(2S,5R)-1-(benzyloxycarbonyl)-2-(11-(benzyloxy)-3-oxo-1-undecenyl)-5-methylpyrrolidine 
• 143064-43-1 (2R,5S)-2-((E)-11-Benzyloxy-3-oxo-undec-1-enyl)-5-methyl-pyrrolidine-1-carboxylic acid benzyl ester 
• 135625-69-3 (2S,5R)-2-Methyl-5-((E)-3-oxo-dec-1-enyl)-pyrrolidine-1-carboxylic acid benzyl ester 
• 143064-44-2 (3R,5S,8S)-5-(8-(benzyloxy)octyl)-3-methylpyrrolizidine 
• 143120-64-3 (Z)-(2R,5S)-1-(benzyloxycarbonyl)-2-methyl-5-(3-oxo-1-decenyl)pyrrolidine 
• 135625-69-3 (E)-(2R,5S)-1-(benzyloxycarbonyl)-2-methyl-5-(3-oxo-1-decenyl)pyrrolidine 

Relevant academic research and scientific papers

A chirospecific synthesis of an ant venom alkaloid (5Z,8E)-3-heptyl-5-methylpyrrolizidine

A straightforward and practical route for the chirospecific synthesis of both enantiomers of the ant venom alkaloid (5Z,8E)-3-heptyl-5-methylpyrrolizidine has been developed.

A new synthesis of ant venom alkaloid: (3S,5R,8S)-3-heptyl-5-methylpyrrolizidine

A highly enantioselective synthesis of (3S,5R,8S)-3-heptyl-5-methylpyrrolizidine is described by using (S)-pyroglutamic acid as starting material.

A Short, Chirospecific Synthesis of the Ant Venom Alkaloid (3R,5S,8S)-3,5-Dialkylpyrrolizidines

The stereospecific synthesis of both (+)-xanovenine (1) and (+)-(3R,5S,8S)-3-methyl-5-(8-nonenyl)pyrrolizidine (2) found in ant venom, is described.The stereoselective intramolecular amidomercuration of the N-alkenylurethane 3, available from D-alanine, f