135625-68-2Relevant articles and documents
A chirospecific synthesis of an ant venom alkaloid (5Z,8E)-3-heptyl-5-methylpyrrolizidine
Takahata,Bandoh,Momose
, p. 351 - 352 (1991)
A straightforward and practical route for the chirospecific synthesis of both enantiomers of the ant venom alkaloid (5Z,8E)-3-heptyl-5-methylpyrrolizidine has been developed.
A new synthesis of ant venom alkaloid: (3S,5R,8S)-3-heptyl-5-methylpyrrolizidine
Grandjean,Rosset,Celerier,Lhommet
, p. 4517 - 4518 (2007/10/02)
A highly enantioselective synthesis of (3S,5R,8S)-3-heptyl-5-methylpyrrolizidine is described by using (S)-pyroglutamic acid as starting material.
A Short, Chirospecific Synthesis of the Ant Venom Alkaloid (3R,5S,8S)-3,5-Dialkylpyrrolizidines
Takahata, Hiroki,Bandoh, Hiroshi,Momose, Takefumi
, p. 4401 - 4404 (2007/10/02)
The stereospecific synthesis of both (+)-xanovenine (1) and (+)-(3R,5S,8S)-3-methyl-5-(8-nonenyl)pyrrolizidine (2) found in ant venom, is described.The stereoselective intramolecular amidomercuration of the N-alkenylurethane 3, available from D-alanine, f